Poly[bis[μ3-2-(1H-tetrazol-1-yl)acetato]cadmium(II)]
نویسندگان
چکیده
In the title compound, [Cd(C(3)H(3)N(4)O(2))(2)](n), the Cd(II) ion, located on a twofold rotation axis, is six-coordinated by two N atoms [Cd-N = 2.368 (2) Å] and four O atoms [Cd-O = 2.300 (1) and 2.260 (1) Å] from six 2-(1H-tetra-zol-1-yl)acetate (L) ligands in a distorted octa-hedral geometry. The metal centres are connected via the tridentate L ligands into a three-dimensional polymeric structure.
منابع مشابه
Poly[[bis[3-(1H-tetrazol-1-yl)propanoic acid-κN 4]cadmium]-di-μ-thiocyanato-κ2 N:S;κ2 S:N]
In the title compound, [Cd(NCS)(2)(C(4)H(6)N(4)O(2))(2)](n), the Cd(II) cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN(-) anions and two N atoms from two 3-(1H-tetra-zol-1-yl)propanoic acid (Htzp) ligands in a distorted octa-hedral geometry. The SCN(-) anions bridge the Cd(II) cations into a layer structure parallel to (100). A weak intra-mole...
متن کاملPoly[[bis{μ3-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)]
In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetra-zole N(4) atoms of six symmetry-equivalent tris-[2-(1H-tetra-zol-1-yl)eth-yl]amine ligands (t(3)z) in the form of a Jahn-Teller-distorted octa-hedron with Cu-N bond distances of 2.0210 (8), 2.0259 (8) and 2.4098 (8) Å. The tertiary amine N atom is stereoc...
متن کاملcatena-Poly[[(acetato-κ2 O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ2 N 3:N 3′-[(acetato-κ2 O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido]
In the title complex, [Cd(2)(CH(3)COO)(2)Cl(2)(C(16)H(14)N(4))(CH(3)OH)(2)](n), the Cd(II) atom is six-coordinated by one N atom from a centrosymmetric bridging 1,2-bis-(2,2'-1H-benzimidazol-2-yl)ethane (bbe) ligand, two O atoms from a chelating acetate ligand, one O atom from a methanol mol-ecule and two bridging Cl atoms in a distorted octa-hedral geometry. The Cd(II) atoms are connected alte...
متن کاملPoly[diaqua-1κ2 O-bis[μ3-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)]
The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydro-thermal reaction of cadmium(II) chloride and 2-(1H-tetra-zol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coordinated by four O and two N atoms from four symmetry-related ligands, forming a trigonal-prismati...
متن کاملcatena-Poly[(trans-diaquacadmium)-bis{μ-5-[4-(1H-imidazol-1-yl)phenyl]tetrazol-1-ido}]
In the title compound, [Cd(C(10)H(7)N(6))(2)(H(2)O)(2)], the Cd(II) atom lies on an inversion centre and is coordinated by four N atoms from 5-[4-(1H-imidazol-1-yl)phen-yl]tetra-zol-1-ide ligands and two O atoms from the coordinated water mol-ecules in an octa-hedral arrangement. The complex polymeric chains are inter-connected via inter-molecular water O-H⋯N hydrogen bonds into a three-dimensi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009